trans-Cp2Mo2O2(μ-O)(μ-Te) | 197311-90-3

• 英文名称: trans-Cp2Mo2O2(μ-O)(μ-Te)
• CAS: 197311-90-3
• 化学式: C₁₀H₁₀Mo₂O₃Te
• 分子量: 497.668
• InChiKey: WMMJOZVEMWUHSO-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  Cp2Mo2Fe2(CO)7(μ3-S)(μ3-Te) 在 air 作用下， 以 苯 为溶剂， 以31%的产率得到trans-Cp2Mo2O2(μ-O)(μ-Te)
  参考文献：
  名称：

  Synthesis and structural characterisation of trans-Cp2Mo2O2(μ-O)(μ-Te) and cis-Cp2Mo2O2(μ-O)(μ-S)

  摘要：

  The two compounds, trans-Cp2Mo2O2(mu-O)(mu-Te) and cis-Cp2Mo2O2(mu-O)(mu-S), were isolated in 31% and 36% yields respectively, when a benzene solution of Cp2Mo2Fe2(CO)(7)(mu(3)-S)(mu(3)-Te) was refluxed for 3 h in the presence of air. Characterisation was carried out by IR, H-1 NMR and Te-125 NMR spectroscopy. The structures, established by single crystal X-ray diffraction analysis, consist of an ore-bridged dimolybdenum unit containing a mu(2)-Te atom in one case and a mu(2)-S atom in the other. Also attached to each Mo atom are a Cp ligand and a terminally bonded oxo group. (C) 1997 Elsevier Science S.A.

  DOI：

  10.1016/s0022-328x(97)00152-6