1-methylpiperazin-4-ium trichloro(1-methylpiperazine-N(4))cobaltate(II) | 220632-60-0

• 英文名称: 1-methylpiperazin-4-ium trichloro(1-methylpiperazine-N(4))cobaltate(II)
• CAS: 220632-60-0
• 化学式: C₅H₁₂Cl₃CoN₂*C₅H₁₃N₂
• 分子量: 366.688
• InChiKey: BIMVQDFIWVHDOL-UHFFFAOYSA-L

反应信息

• 作为产物：
  描述：

  N-甲基哌嗪 、 cobalt(II) chloride hexahydrate 以 乙醇 为溶剂， 以2.2%的产率得到1-methylpiperazin-4-ium trichloro(1-methylpiperazine-N(4))cobaltate(II)
  参考文献：
  名称：

  Cobalt(II) complexes of piperazine and derivatives: 1-methylpiperazin-4-ium trichloro(1-methylpiperazine-N⁴)cobaltate(II)

  摘要：

  The title compound, (C5H13N2)[CoCl3(C5H12N2)], contains a Co-II ion coordinated to three Cl atoms and to the unmethylated N atom of N-methylpiperazine in a distorted tetrahedral geometry. The six-membered ring of both the coordinated and free N-methylpiperazine molecules possesses the more stable chair conformation, In addition, other tautomeric forms may be present in small amounts in the crystals.

  DOI：

  10.1107/s0108270198009603