| 192648-48-9

• CAS: 192648-48-9
• 化学式: C₁₈H₃₄CoO₃P
• 分子量: 388.433
• InChiKey: WJROCSYRCGUNQV-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  dicobalt hexacarbonyl bis(tri-n-butylphosphine) 、 丁酰氯 在 sodium amalgam 作用下， 以 乙醚 为溶剂， 生成
  参考文献：
  名称：

  The behaviour of n- and iso-propylcobalt tricarbonyl tributylphosphine complexes under hydroformylation conditions

  摘要：

  Tributylphosphine n-propyl- (Ia) and iso-propyl (Ib) cobalt tricarbonyl have been prepared from NaCo(CO)(3)(PBu3) and the proper alkyl halide. The behaviour of Ia and Tb under hydroformylation conditions (T = 120-180 degrees C, p(CO) = 5 atm, p(H2) = 50 atm in the presence or absence of an excess of an olefin or PBu3) has been tested. Ia and Tb gave the expected isomeric alcohols with a selectivity higher than 95%. The role of these complexes in the hydroformylation reaction has been discussed. (C) 1997 Elsevier Science S.A.

  DOI：

  10.1016/s0022-328x(97)00009-0