| 173603-47-9

• CAS: 173603-47-9
• 化学式: C₁₂H₈BiCl₂*C₃₆H₃₀NP₂
• 分子量: 970.67
• InChiKey: MFDDXJSNIXVMCW-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  、 氯化铋 、 双(三苯基正膦基)氯化铵 以 四氢呋喃 、 乙醚 为溶剂， 以70%的产率得到
  参考文献：
  名称：

  Synthesis, Structures, and Reactivity of Biphenylylene Complexes of Bismuth(III)

  摘要：

  The synthesis of [Bi-2(biph)(3)] (5) and [PPN]-[BiCl2(biph)] (6) (biph=2,2'-biphenylylene, PPN=Ph(3)P=N=PPh(3)), the first structurally characterized biphenylylene complexes of bismuth (III), are described. Complex 5 crystallizes as a THF (tetrahydrofuran) solvate; each bismuth is three-coordinate with a trigonal pyramidal geometry. The solid state of 6 comprises separated [PPN](+) cations and [BiCl2(biph)](-) anions. The anion adopts a trigonal bipyramidal geometry at the bismuth; the axial sites are occupied by chloride ligands, and two of the tree equatorial sites are occupied by ring carbon atoms.

  DOI：

  10.1021/om950734y