Ir(1-σ-3-η(3)-pentenyl)[N(SiMe2CH2PPh2)2] | 168000-37-1

• 英文名称: Ir(1-σ-3-η(3)-pentenyl)[N(SiMe2CH2PPh2)2]
• CAS: 168000-37-1
• 化学式: C₃₅H₄₄IrNP₂Si₂
• 分子量: 789.08
• InChiKey: JXZKBBGFUDOWMV-PTDWBMLLSA-N

反应信息

• 作为产物：
  描述：

  [Ir(CH2)(κ(3)-N(Si(CH3)2CH2P(C6H5)2)2)] 、 1,3-丁二烯 以 甲苯 为溶剂， 以86%的产率得到Ir(1-σ-3-η(3)-pentenyl)[N(SiMe2CH2PPh2)2]
  参考文献：
  名称：

  1，3-丁二烯与铱亚甲基配合物Ir：CH2 [N（SiMe2CH2PPh2）2]的化学计量均相

  摘要：

  The reaction of the iridium methylene complex Ir=CH2[N(SiMe(2)CH(2)PPh(2))(2)] with 1,3-butadiene leads to the formation of a new complex with the formula Ir(C5H8)[N(SiMe(2)CH(2)PPh(2))(2)] in which 1 equiv of butadiene has been incorporated. By a series of NMR experiments, the structure was established as containing a sigma-eta 3-pentenyl unit. The X-ray crystal structure confirms the stereochemistry of the hydrocarbyl unit as being anti-exo, with the tridentate ancillary ligand adopting the facial orientation. Labeling studies indicate that the formation is diastereoselective as a result of the orientation of the incoming double bond in the early stages of the reaction mechanism.

  DOI：

  10.1021/om00009a028