[Ru(5-chlorophen)(bpy)2](PF6)2 | 102630-17-1

• 英文名称: [Ru(5-chlorophen)(bpy)2](PF6)2
• 英文别名: [Ru(5-chloro-1,10-phenanthroline)(bipyridine)2](PF6)2
• CAS: 102630-17-1
• 化学式: C₃₂H₂₃ClN₆Ru*2F₆P
• 分子量: 918.026
• InChiKey: NDQOOLGCTWTHAH-UHFFFAOYSA-N

反应信息

• 作为反应物：
  描述：

  [Ru(5-chlorophen)(bpy)2](PF6)2 在 四(三苯基膦)镍 锌 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 以65%的产率得到tetrakis(2,2'-bipyridine)(5,5'-bis(1,10-phenanthroline))diruthenium(II) hexafluorophosphate
  参考文献：
  名称：

  金属催化偶联反应制备的新型发光和氧化还原同金属双核铱(III)、钌(II)和锇(II)配合物

  摘要：

  制备了四种新的同金属双核IrIII、RuII和OsII配合物，并报道了它们的发光性质和氧化还原行为；由于其不寻常的非平面结构，发现双菲咯啉桥接配体可分离每个双核系统的两个组分。

  DOI：

  10.1039/b006456o

文献信息

• Ruthenium Complexes That Break the Rules:  Structural Features Controlling Dual Emission
  作者：Edith C. Glazer、Douglas Magde、Yitzhak Tor

  DOI：10.1021/ja071124f

  日期：2007.7.1

  A family of heteroleptic Ru-II coordination complexes containing substituted 1,10-phenanthroline (phen) ligands with extended conjugation was found to exhibit two simultaneously emissive excited states at room temperature in fluid solution. These systems demonstrate a breakdown of the standard nonradiative decay pathways that normally lead to a single, dominant, lowest energy emissive excited state in Ru-II complexes and most other chromophores. The structural requirements for dual emission were explored through the synthesis and characterization of isomeric systems. Two features were found to be primarily responsible for resolvable dual emission. Extended conjugation at the 4-position of the 1,10-phenanthroline ligand was identified as an essential feature, and asymmetry in the phenanthroline ligand substitutions appears to greatly facilitate the production of these two nonequilibrated emissive states. Additional complexes were studied which displayed "tunable" emissive characteristics for the two excited states as a function of covalent and noncovalent modification.