| 1253783-17-3

• CAS: 1253783-17-3
• 化学式: C₃₀H₇₀N₆O₂Zn₂
• 分子量: 677.705
• InChiKey: QRAYALFACZRGNO-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
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• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  3-乙基-3-戊醇 、 以 甲苯 为溶剂， 以50%的产率得到
  参考文献：
  名称：

  Synthesis and structures of zinc alkoxo, aryloxo and hydroxo complexes with an amidodiamine ligand

  摘要：

  The synthesis and characterization of zinc complexes bearing an amidodiamine ligand, (EtO)(4)Zn(3)[N(CH(2)CH(2)NMe(2))(2)](2) (1), [Et(3)CO)ZnN(CH(2)CH(2)NMe(2))(2)](2) (2) and [(2,6-(i)Pr(2)C(6)H(3)O)ZnN(CH(2)CH(2) NMe(2))(2)](2) (3), [(Me(3)Si)(2)N]Zn[N(CH(2)CH(2)NMe(2))(2)] (4) and [(Me(3)Si)(2)N](2)Zn(2)(OH)[N(CH(2)CH(2)NMe(2))(2)] (5), are reported. Compounds 1-3 are synthesised in the reactions of {Zn[N(CH(2)CH(2)NMe(2))(2)](2)}(2) with 2 equiv. of ethanol, 3-ethyl-3-pentanol and 2,6-diisopropylphenol, respectively. Compound 4 is obtained by the reaction of Zn[N(SiMe(3))(2)](2) with HN(CH(2)CH(2)NMe(2))(2), and compound 5 is synthesised by reacting 4 with 1 equiv. of H(2)O. Compound 4 is characterized by NMR and MS while all of the other compounds are characterized with NMR, MS, elemental analysis and single-crystal X-ray diffraction. Compound 1 is a trinuclear species containing a Zn(3)N(2)O(2) core. Compounds 2 and 3 are dimeric with planar Zn(2)N(2) rings. Compound 5 is dimeric with a planar Zn(2)NO ring. (C) 2010 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2010.06.029