[ReCl3(PPh3)2(NC6H4OH)]*THF | 1159255-29-4

• 英文名称: [ReCl3(PPh3)2(NC6H4OH)]*THF
• CAS: 1159255-29-4
• 化学式: C₄H₈O*C₄₂H₃₅Cl₃NOP₂Re
• 分子量: 996.366
• InChiKey: RSSVBURDALMSCN-UHFFFAOYSA-K

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  四氢呋喃 、 trans-[ReOCl3(PPh3)2] 、 Ph2P(O)C6H4-2-HCN(C6H4-2-OH) 生成 [ReOCl2(PPh3)(Ph2P(O)C6H4-2-HCN(C6H4-2-O)] 、 [ReCl3(PPh3)2(NC6H4OH)]*THF
  参考文献：
  名称：

  Heterofunctionalized phosphines derived from (2-formylphenyl)diphenylphosphine and their reactions with oxorhenium(V) complexes

  摘要：

  Reactions of [ReOCl3(PPh3)(2)] with a potentially tridentate Schiff base derived from (2-formylphenyl)diphenylphosphine and 2-aminophenol, (HLP)-P-1, ((HLP)-P-1=Ph2PC6H4-2-HC=N(C6H4-2-OH) result in a rapid decomposition of the Schiff base and the formation of a large number of hitherto non-identified metal-containing species, while from similar reactions with the analogoue phosphine oxide (HLPO)-P-1. (HLPO)-P-1 = Ph2P(O)C6H4-2-HC=N(C6H4-2-OH)) products of the compositions [ReOCl2(PPh3)((LPO)-P-1)] (1) and [Re(NC6H4-2-OH)Cl-3(PPh3)(2)] (2) could be isolated. The structure of 2 is an experimental proof of the preceding, metal-induced cleavage of the C-N double bond. A subsequent reaction of the released 2-aminophenol forms the final phenylimido ligand.Reduction of (HLP)-P-1 with NaBH4 gives the phosphine amine (H2LP)-P-2(H2L2 = Ph2P(C6H4-2-CH2NH(C6H4-2-OH))) in good yield. Reactions of H(2)L(2)p Wit h common oxorhenium(V) complexes result in the formation of the stable rhenium(V) complex [ReOCl2((HLP)-P-2)] (3) with a facially coordinated HL2P ligand. (C) 2009 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2009.01.016