[Zn(2-(3,5-dimethylpyrazol-1-ylmethyl)pyridine)(μ_1,1-N₃)(N₃)]₂ | 1551079-63-0

• 英文名称: [Zn(2-(3,5-dimethylpyrazol-1-ylmethyl)pyridine)(μ_1,1-N₃)(N₃)]₂
• 英文别名: [Zn(DMP)(μ_1,1-N₃)(N₃)]₂
• CAS: 1551079-63-0
• 化学式: C₂₂H₂₇N₁₈Zn₂
• 分子量: 674.357
• InChiKey: MBWGMDHYILURSU-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  2-(3,5-dimethylpyrazol-1-ylmethyl)pyridine 、 zinc perchlorate 、 sodium azide 以 甲醇 为溶剂， 反应 0.25h， 生成 [Zn(2-(3,5-dimethylpyrazol-1-ylmethyl)pyridine)(μ_1,1-N₃)(N₃)]₂
  参考文献：
  名称：

  Cadmium(II) and zinc(II) azido complexes with different nuclearity and dimensionality

  摘要：

  The reaction of Cd(ClO4)(2)center dot 6H(2)O with the tetradentate tripod amine BPQA (bis(2-methylpyridyl)-2-methylquinolyl-amine) afforded the mononuclear complex [Cd(BPQA)(N-3)(2)] (1), whereas its reaction with the bidentate amines Et(2)Meen (N,N-diethyl-N'-methylethylenediamine) and DMP (2-(3,5-dimethylpyrazol-1-ylmethyl)pyridine) resulted in the formation of different bridged-azido polymeric 2D- and 1D-chains [Cd-2(Et(2)Meen)2(mu(1,1)-N-3)(2)(mu(1,3)-N-3)(2)](n) (2) and [Cd(DMP)(mu(1,1)-N-3)(2)](n) (3), respectively. The reaction of Zn(ClO4)(2)center dot 6H(2)O with DMP led to the isolation of the doubly bridged EO-azido dinuclear complex [Zn(DMP)(mu(1,1)-N-3)(N-3)](2) (4). The four complexes have been structurally characterized by elemental microanalyses, IR spectroscopy and by single crystal X-ray crystallography. The luminescence properties of [Cd(BPQA)(N-3)] (1) complex and its ligand, BPQA were investigated, where the complex revealed strong fluorescence enhancement. (C) 2013 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2013.11.019