[(C5Me5)RhCl(η(3)-syn-1-methylallyl)] | 32660-85-8

• 英文名称: [(C5Me5)RhCl(η(3)-syn-1-methylallyl)]
• CAS: 32660-85-8
• 化学式: C₁₄H₂₂ClRh
• 分子量: 328.687
• InChiKey: UAOMPMWIBXEPSA-UHFFFAOYSA-M

反应信息

• 作为产物：
  描述：

  dichloro(pentamethylcyclopentadienyl)rhodium (III) dimer 、 乙烯基溴化镁 以 四氢呋喃 为溶剂， 以52%的产率得到[(C5Me5)RhCl(η(3)-syn-1-methylallyl)]
  参考文献：
  名称：

  Vinyl-plus-vinyl coupling in rhodium complexes: formation of [(C5Me5)RhBr(η3-syn-1-methylallyl)] be reaction of [(C5Me5)RhBr2(Me2SO)] with vinylmagnesium bromide in homogeneous solution

  摘要：

  The syn-1-methylallyl complex [(C(5)Me(5))RhBr(eta(3)-CH(2)CHCHMe)] was obtained by reaction of [(C(5)Me(5))RhBr2(Me(2)SO)] with vinylmagnesium bromide, via a vinyl-plus-vinyl coupling. This reaction is related to the vinyl-plus-vinyl coupling reactions of vinyl bromide on rhodium particles under Fischer-Tropsch conditions.

  DOI：

  10.1016/0022-328x(94)00029-c