bis(μ2,η2-2-chloro-4-ferrocenylbenzoate)(1,10-phenanthroline)lead(II) - methanol - water (1/1/1) | 1235861-57-0

• 英文名称: bis(μ2,η2-2-chloro-4-ferrocenylbenzoate)(1,10-phenanthroline)lead(II) - methanol - water (1/1/1)
• CAS: 1235861-57-0
• 化学式: CH₄O*C₄₆H₃₂Cl₂Fe₂N₂O₄Pb*H₂O
• 分子量: 1116.63
• InChiKey: RPYIEXIAZVSVOJ-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  甲醇 、 1,10-菲罗啉 、 sodium 2-chloro-4-ferrocenylbenzoate 、 lead(II) acetate trihydrate 以 甲醇 为溶剂， 以38%的产率得到bis(μ2,η2-2-chloro-4-ferrocenylbenzoate)(1,10-phenanthroline)lead(II) - methanol - water (1/1/1)
  参考文献：
  名称：

  Two distinct ferroceneyl carboxylate Pb(II) complexes with the same composition prepared by two different synthetic methods: The substitution of precursor and one-pot reaction

  摘要：

  Through substituation reaction. one lead ferroceneyl carboxylate polymer, namely [Pb(mu(2)-OOCCIH3-Cr(6)Fc)(2)(phen)](n) la [Fc = (eta(5)-C5H5)Fe(eta(5)-C5H4)] was synthesized from precursor [Pb(mu(2)-eta(2)-OOCCIH(3)C(6)fC)(2)- (CH3OH)(2)](n). However, a mononuclear Pb(II) complex [Pb(mu(2)-OOCCIH3-Cr(6)Fc)(2)(phen)](n) (CH3OH) (H2O)) 2 could be obtained from the traditional one-pot reaction of FcC(6)H(3)ClCOONa and Pb(OAc)(2) with 1,10-phenantholine (phen). The electrochemical Studies of 1, 1a, 2 and FcC(6)H(3)CICCOH indicate that the half-wave potentials of the ferrocenyl moieties in these complexes are all shifted to positive potential compared with that of FcC(6)H(3)CICOOH (C) 2010 Elsevier B V All rights reserved

  DOI：

  10.1016/j.inoche.2010.01.006