Cp(*)2Ir2Cl3H | 41380-03-4

• 英文名称: Cp(*)2Ir2Cl3H
• 英文别名: [(Cp*IrCl)2(μ2-H)(μ2-Cl)]；[(Cp*IrCl)2HCl]
• CAS: 41380-03-4
• 化学式: C₂₀H₃₁Cl₃Ir₂
• 分子量: 762.265
• InChiKey: GCLKXWIVBVHDHD-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  锂硼氢 、 Cp(*)2Ir2Cl3H 生成 Cp(*)Ir(H)2B3H7
  参考文献：
  名称：

  Novel Iridaboranes from the Reactions of Cp*₂Ir₂H_xCl_4-x, x = 0−2, with LiBH₄. Existence of a Concurrent Reaction Channel in the Conversion of Metal Chlorides to Metal Hydrides

  摘要：

  Reaction of either Cp*2Ir2Cl4 or Cp*2Ir2HCl3 with LiBH4 leads to formation of the new iridaborane Cp*Ir(H)(2)B3H7, 1 (a borallyl complex), in parallel with Cp*IrH4. In contrast, reaction, of Cp*2Ir2H2Cl2 with LiBH4 leads exclusively to Cp*Ir-2(2)(H)(3)B2H5, 3, which is isolobal with 1.

  DOI：

  10.1021/om990091c
• 作为产物：
  描述：

  四氯化碳 、 Cp(*)Ir(H)4 以 苯 为溶剂， 生成 Cp(*)2Ir2Cl3H 、 ((C5(CH3)5)IrCl)2(μ-H)2
  参考文献：
  名称：

  四氢（五甲基环戊二烯基）铱的制备与反应：一种新型的铱（V）多羟基化合物

  摘要：

  DOI：

  10.1021/om50004a037

文献信息

• Mechanistic Investigations of the Iridium(III)-Catalyzed Aerobic Oxidation of Primary and Secondary Alcohols
  作者：Bi Jiang、Yuee Feng、Elon A. Ison

  DOI：10.1021/ja8049595

  日期：2008.11.5

  The commercially available catalysts [(Cp*IrCl2)(2)] is employed with O-2 as the terminal oxidant in the presence of catalytic amounts of Et3N for the aerobic oxidation of primary and secondary alcohols. A new mechanism for the Ir-catalyzed aerobic oxidation is also presented that suggests that the transition metal maintains its +3 oxidation state throughout the entire catalytic cycle.
• Acid–Base Bifunction and Umpolung of the Bridging Hydride in a Coordinatively Unsaturated Mesylimido- and Hydrido-Bridged Diiridium Complex
  作者：Hiroko Arita、Koji Ishiwata、Shigeki Kuwata、Takao Ikariya

  DOI：10.1021/om7009705

  日期：2008.2.1

  The mono(mesylamido)-bridged diiridium(III) complex [(CP*IrCl)(2)(mu(2)-H)(mu(2)-NHMS)] (CP* = eta(5)-C-5(CH3)(5), MS = SO2CH3) undergoes reversible dehydrochlorination to afford the unsaturated imido-bridged dinuclear complex [Cp*Ir(mu H2-)(mu(2)-NMs)IrClCP*] (2) The reaction of 2 with trimethylphosphine gives the simple adduct [Cp*Ir[P(CH3)(3)}(mu(2)-H)(mu(2)-NMs)IrClCp*], while the reaction with CO results in sequential formation of the mono- and dicarbonyl Ir(II) complexs [Cp*Ir(CO)(mu(2)-NHMs)IrClCp*] and [Cp*Ir(CO)}(2)(mu(2)-NMs)] and with concomitant umpolung of the bridging hydrido ligand in 2 to the amido proton.