[PtCl2(NC5H4CH=NC6H4-3-CO2H)] | 656230-04-5

• 英文名称: [PtCl2(NC5H4CH=NC6H4-3-CO2H)]
• CAS: 656230-04-5
• 化学式: C₁₃H₁₀Cl₂N₂O₂Pt
• 分子量: 492.221
• InChiKey: PGIGOVVSYNWGER-SFRYUHGMSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  bis(benzonitrile)dichloroplatinum(II) 、 3-[(1-pyridin-2-yl-methylidene)-amino]benzoic acid 以 四氢呋喃 为溶剂， 以82%的产率得到[PtCl2(NC5H4CH=NC6H4-3-CO2H)]
  参考文献：
  名称：

  Palladium(II) and platinum(II) complexes containing hydrophilic pyridinylimine-based ligands

  摘要：

  Reaction of the unsymmetrical hydrophilic pyridinylimine ligands 1a-e with either PdCl2(C6H5CN)(2) or PtCl2(C6H5CN)(2) affords the square-planar d(8) dichloride complexes 2a-e and 3, respectively. Formation of these divalent species effectively stabilizes the reactive imine bond towards hydrolysis. All of the Pd(II) and Pt(II) complexes were characterized by H-1 and C-13 NMR spectroscopy and elemental analysis. The solid-state structure of 2a was established by X-ray crystallography and reveals relatively little delocalization of the imine C=N bond upon metallacycle formation. (C) 2003 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0020-1693(03)00304-9