{η6-(3-fluoro-2-methoxyaniline)}tricarbonylchromium | 141967-06-8

• 英文名称: {η6-(3-fluoro-2-methoxyaniline)}tricarbonylchromium
• CAS: 141967-06-8
• 化学式: C₁₀H₈CrFNO₄
• 分子量: 277.172
• InChiKey: MLSKIZDZKSWUTG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  3-氟-2-甲氧基苯胺 、 六羰基铬 以57%的产率得到{η6-(3-fluoro-2-methoxyaniline)}tricarbonylchromium
  参考文献：
  名称：

  The prediction of the 19F NMR spectra of fluoro-substituted arenetricarbonylchromium complexes

  摘要：

  The tricarbonylchromium complexes of the following derivatives of fluorobenzene have been prepared: 2,4- and 3,5-dimethyl-, 2,4,6-trimethyl-, 3,4- and 3,5-dimethoxy- and 4-methoxy-2-methylfluorobenzene, 4-fluorocumene, 4-fluoro-N,N-dimethylaniline, 3-fluoro-2-methoxyaniline and 4-fluoro-2-methylacetophenone. Preparative, microanalytical, IR, UV-Vis and H-1 and F-19 NMR spectral data are presented for these new compounds. Both literature and new F-19 NMR spectral data have been analysed for thirty-five monofluoro complexes and seven difluoro complexes. A statistical prediction method for both these types of complexes is presented with correlation coefficients of observed versus predicted line positions of 0.986 and 0.993, respectively.

  DOI：

  10.1016/s0020-1693(00)93460-1