| 197444-75-0

• CAS: 197444-75-0
• 化学式: C₇₂H₅₆Fe₂Ir₄O₄P₄
• 分子量: 1989.7
• InChiKey: ZDLJTFDPRDVCOA-OAXWVMCFSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  1,1'-双(二苯基膦)二茂铁 、 羰基铱 以 甲苯 为溶剂， 以5.5%的产率得到
  参考文献：
  名称：

  A novel octa-substituted iridium carbonyl derivative containing the dehydrogenated dppf ligand (dppf=Fe(C5H4PPh2)2): synthesis and crystal structure of [H4Ir4(CO)4{Fe(C5H3PPh2)(C5H4P(Ph)C6H4)}2]

  摘要：

  The octa-substituted iridium carbonyl derivative [H4Ir4(Co)(4){Fe(C5H3PPh2) (C5H4P(Ph)C6H4)}(2)] prepared from [Ir-4(CO)(12)] and dppf consists of a tetrahedral Ir-4 unit and two tetradentate dehydrogenated dppf ligands formed upon ortho-metallation of a cyclopentadienyl and a phenyl ring with each iridium atom coordinated by a carbonyl group, a phosphorus and an ortho-carbon of the dehydrogenated cyclopentadienyl or phenyl group.

  DOI：

  10.1016/s0020-1693(97)05694-6