| 581104-91-8

• CAS: 581104-91-8
• 化学式: C₂₁H₃₂Cl₂FeNO
• 分子量: 441.244
• InChiKey: PISJNYRQRNTESD-UZCIDVFDSA-K

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  、 三氯化铁 以 not given 为溶剂， 生成
  参考文献：
  名称：

  Design of Highly Active Iron-Based Catalysts for Atom Transfer Radical Polymerization:  Tridentate Salicylaldiminato Ligands Affording near Ideal Nernstian Behavior

  摘要：

  Iron(II) complexes bearing monoanionic tridentate salicyladiminato ligands are shown to be highly efficient catalysts for atom transfer radical polymerization (ATRP). Polymerization rates for styrene are among the highest reported for iron-mediated ATRP in nonpolar media, correlating well with E1/2 potentials and DeltaEp values for the complexes. The rigidity of the tridentate ligands, combined with ample space around the metal center to accommodate a halogen atom, we believe to be an important factor in the efficient ATRP behavior of these systems.

  DOI：

  10.1021/ja035458q