| 1451192-47-4

• CAS: 1451192-47-4
• 化学式: C₁₇H₂₁Cl₂N₅RuS
• 分子量: 499.429
• InChiKey: QTSMNLOWHKJIRK-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  4-氨基-5-吡啶-4H-三唑硫醇 、 [ruthenium(II)(η⁶-1-methyl-4-isopropyl-benzene)(chloride)(μ-chloride)]₂ 以 四氢呋喃 为溶剂， 反应 2.0h， 以91%的产率得到
  参考文献：
  名称：

  Synthesis and Catalytic Activity of Semiconducting p-Cymene Ruthenium 1,3,4-Thiadiazole and 1,2,4-Triazole Complexes

  摘要：

  The novel ruthenium(II) complexes containing 5-(pyridin-4-yl)-1,3,4-thiadiazol-2-amine(1) and 4-amino-5-(pyridin-4-yl)-4H-1,2,4-triazole-3-thiol (2) ligands were synthesized and characterized by UV-Vis, IR, NMR, and elemental analysis. The complexes have been employed as catalysts for the transfer hydrogenation of acetophenone in the presence of KOH using 2-propanol as a hydrogen source at 82 degrees C. Moreover, the temperature dependence of conductivity of the complexes was determined in the temperature range of 303373K. The complex [Ru(1,2)(p-cymene)Cl-2] exhibits the semiconducting behavior, as the conductivity of the samples is increased with the increase in temperature.

  DOI：

  10.1080/15533174.2012.751421