[PtCl(4-(n-C12H25)-C6H2-1,3-(OPiPr2)2)] | 1210500-90-5

• 英文名称: [PtCl(4-(n-C12H25)-C6H2-1,3-(OPiPr2)2)]
• CAS: 1210500-90-5
• 化学式: C₃₀H₅₅ClO₂P₂Pt
• 分子量: 740.246
• InChiKey: QTGMUZCIUIYTPM-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  dichlorobis(dimethylsulfide)platinum(II) 、 4-(n-C12H25)-C6H3-1,3-(OP-iPr2)2 以 甲苯 为溶剂， 以81.2%的产率得到[PtCl(4-(n-C12H25)-C6H2-1,3-(OPiPr2)2)]
  参考文献：
  名称：

  Group 10 phosphinite POCOP pincer complexes derived from 4-n-dodecylresorcinol: An alternative way to produce non-symmetric pincer compounds

  摘要：

  Phosphinite POCOP pincer compounds 14-(n-C12H25)-C-6-H-3-1,3-(OPR2)(2)] R=Ph (1), Pr-i (2) derived from 4-n-dodecylresorcinol and their group 10 derivatives [MCI{3-(n-C12H25)-C6H2-2,6-(OPR2)(2)}] M(R) = Ni(Ph) (3), Ni(Pr-i) (6), Pd(Ph) (4), Pd(Pr-i) (7) and Pt(Ph) (5), Pt(Pr-i) (8) were synthesized and the catalytic activity of the palladium species explored in the Mizoroki-Heck and Suzuki-Miyaura cross coupling reactions. (C) 2009 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2009.07.038