[Bi(C6F5)(W(CO)3(η-C5H5))2] | 168130-24-3

• 英文名称: [Bi(C6F5)(W(CO)3(η-C5H5))2]
• CAS: 168130-24-3
• 化学式: C₂₂H₁₀BiF₅O₆SW₂
• 分子量: 1074.06
• InChiKey: AHZTXWJNKVXSKH-UHFFFAOYSA-M

反应信息

• 作为产物：
  描述：

  tris(pentafluorophenylmercapto)bismuth 、 [Bi(W(CO)3(η-C5H5))3] 以 四氢呋喃 为溶剂， 以56%的产率得到[Bi(C6F5)(W(CO)3(η-C5H5))2]
  参考文献：
  名称：

  Neutral thiolates of antimony(III) and bismuth(III)

  摘要：

  A range of bismuth(III) and antimony(III) thiolates, Bi(SR)(3) (R = C6F5, 4-MeC(6)H(4), 2,6-Me(2)C(6)H(3) or 3,5-Me(2)C(6)H(3)) and Sb(SR)(3) (R = 4-MeC(6)H(4) or 3,5-Me(2)C(6)H(3)) has been synthesised and the structures of the two antimony complexes have been determined. Both structures reveal a trigonal-pyramidal antimony centre bonded to three thiolate groups with; far the 4-MeC(6)H(4) complex. additional intermolecular Sb ... S interactions and, for the 3,5-Me(2)C(6)H(3) complex intermolecular arene to antimony interactions. The syntheses and structures of the organotransition-metal complexes [Bi(SC6F5){M(CO)(3)(eta-C5H5)}(2)] (M = Mo or W) are also reported in which the bismuth centre is bonded to one SC6F5 group and two M(CO)(3)(eta-C5H5) fragments with no short intermolecular interactions.

  DOI：

  10.1039/dt9950002129