mer,trans-[RuCl2(PPh3)(Ph2CH2C(t-Bu)=N-N=CH(C6H4F-2))] | 162973-33-3

• 英文名称: mer,trans-[RuCl2(PPh3)(Ph2CH2C(t-Bu)=N-N=CH(C6H4F-2))]
• CAS: 162973-33-3
• 化学式: C₄₃H₄₁Cl₂FN₂P₂Ru
• 分子量: 838.734
• InChiKey: KWFFOQAQUVLTRI-ABKTVIAYSA-L

反应信息

• 作为产物：
  描述：

  tris(triphenylphosphine)ruthenium(II) chloride 、 N-[1-[(Diphenylphosphanyl)-methyl]-2,2-dimethyl-prop-(Z)-ylidene]-N'-[1-(2-fluoro-phenyl)-meth-(E)-ylidene]-hydrazine 以 苯 为溶剂， 以69%的产率得到mer,trans-[RuCl2(PPh3)(Ph2CH2C(t-Bu)=N-N=CH(C6H4F-2))]
  参考文献：
  名称：

  A systematic method of promoting an aryl fluoride to coordinate to ruthenium(11)

  摘要：

  The phosphino hydrazone Z-PPh(2)CH(2)C(Bu(t))=NNH2 (I) condenses with 2,6-difluorobenzaldehyde to give Z,E-PPh(2)CH(2)C(Bu(t))=N-N=CH(C6H3F2-2,6) (2a), which reacts rapidly with the labile ruthenium(If) complex [RuCl2(PPh(3))(3)] to give mer, trans-[RuCl2(PPh(3)){PPh(2)CH(2)C(Bu(t)) =N-N=CH(C6H3F2-2,6)] (3a). In the F-19{H-1} NMR spectrum of 3a the fluorines are coupled equally to P-A but are not coupled to PB. In the P-31{H-1} NMR spectrum, P-A is coupled equally to both fluorines, i.e. there is a dynamic system with both fluorines coordinated to ruthenium in turn and coupled to P-A, (2)J(PAF)=68 Hz. Similar condensations of 1 with other fluorine-substituted benzaldehydes, viz. pentafluorobenzaldehyde, 2-chloro-6-fluorobenzaldehyde, 2-fluorobenzaldehyde, 2,3-difluorobenzaldehyde, gave mixed azine phosphines. In each case these mixed azine phosphines when treated with [RuCl2(PPh(3))(3)], displaced two tripbenylphosphines to give terdentate chelates showing fluorine coordination to ruthenium. Proton, P-31{H-1} and F-19{1H} NMR data are given and discussed.

  DOI：

  10.1016/0020-1693(94)04156-p