| 188492-19-5

• CAS: 188492-19-5
• 化学式: C₃₀H₂₆Cl₂N₂Pd₂S₂
• 分子量: 762.428
• InChiKey: YSDGUPYYDBSVHO-SCLVERRMSA-L

反应信息

• 作为产物：
  描述：

  lithium chloride 、 以 氯仿 、 丙酮 为溶剂， 以45%的产率得到
  参考文献：
  名称：

  Synthesis and spectroscopic characterization of binuclear thioazomethine palladacycles

  摘要：

  Several 1,2-bis(2-thio(N-benzylidene)anilines)ethane [(RC(6)H(4)CH = NC6H4SCH2)(2)] (4) and 1,3-bis(2-thio(N-benzylidene)anilines)propane [(RC(6)H(4)CH = NC6H4SCH2)(2))(2)CH2] (5), R = H (a), 11-CH3 (b), 11-OCH3 (c), 11-Cl (d) and 11-NO2 (e)] have been synthesized and reacted with Pd(OAc)(2) in boiling benzene. The binuclear cyclopalladated acetato complexes (8/9) thus obtained reacted with LiCl, giving the chloro complexes having the coordination sphere [Pd(C,N,S)Cl-2](2) (10/11). The mod of ligand binding was established using high-resolution H-1 NMR and IR data. Copyright (C) 1997 Elsevier Science Ltd.

  DOI：

  10.1016/s0277-5387(96)00422-6