[Ag(hexakis(tolylsulfanyl)benzene)PF6 | 408317-17-9

• 英文名称: [Ag(hexakis(tolylsulfanyl)benzene)PF6
• CAS: 408317-17-9
• 化学式: Ag*C₄₈H₄₂S₆*F₆P
• 分子量: 1064.09
• InChiKey: UALVCOVADJRQDQ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  六氟磷酸银 、 六[(4-甲基苯基)硫代]苯 以 丙酮 为溶剂， 以43%的产率得到[Ag(hexakis(tolylsulfanyl)benzene)PF6
  参考文献：
  名称：

  A zigzag chain coordination polymer consisting of silver(I) ion having square planar geometry

  摘要：

  Silver(l) complexes of hexakis (tolylsulfanyl) benzene (htsb), [Ag(htsb)](PF6) (1), have been prepared and their molecular structures were determined by X-ray crystallography. In 1, the silver ion prefers a square planar coordination geometry comprized of four S atoms from two different htsb molecules and producing a zigzag chain structure of Ag-S in the silver coordination polymer, Based on the thermo-gravimetry analysis results, two tolylsulfanyl groups were easily eliminated at approximately 211 degreesC. However, [Ag(htsb)(2-butanone)] (PF6) (2), which were obtained by the reactions in different solvents, showed a different colors and thermal degradation behaviors. (C) 2002 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0020-1693(01)00719-8