[ReBr(PPh3)2(onn)]Br | 1226778-29-5

• 英文名称: [ReBr(PPh3)2(onn)]Br
• 英文别名: [ReBr(PPh3)2(2-(2-aminobenzylideneimino)phenol(-3H))]Br
• CAS: 1226778-29-5
• 化学式: Br*C₄₉H₃₉BrN₂OP₂Re
• 分子量: 1079.82
• InChiKey: ZAABOGLNHSLNRN-DVZITXFKSA-K

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  oxotribromobis(triphenylphosphine)rhenium(V) 、 2-hydroxy-N-(2-nitrobenzylidene)-aniline 以 乙醇 为溶剂， 以60%的产率得到[ReBr(PPh3)2(onn)]Br
  参考文献：
  名称：

  Rhenium(I), (III) and (V) complexes of tridentate ONX (X=O, N, S)-donor Schiff bases

  摘要：

  The reactions of the potentially tridentate Schiff bases 2-[(2-hydroxyphenyl)iminomethyl]phenol (H(2)ono) and 2-(2-aminobenzylideneimino)phenol (H(3)onn) with trans-[ReOBr3(PPh3)(2)] were studied, and the complexes [(ReBr)-Br-III(PPh3)(2)(ono)] (1) and [(ReBr)-Br-V(PPh3)(2)(onn)]Br (2) were isolated. In 1 ono acts as a dianionic tridentate ligand, and in 2 onn is coordinated as a tridentate trianionic imido-imino-phenolate. The complex [Re-I(CO)(3)(ons)(Hno)] was isolated from the reaction of [Re(CO)(5)Br] with 2-[(2-methylthio)benzylideneimino]phenol (Moos; Moo = 2-aminophenol), with ons coordinated as a bidentate chelate with a free SCH3 group. These complexes were characterized by X-ray crystallography, NMR and IR spectroscopy. (C) 2010 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2010.01.013