bis-[(4-N,N-dimethylaminophenyl)(dimethyl)silylmethyl](cycloocta-1,5-diene)platinum(II) | 164856-06-8

• 英文名称: bis-[(4-N,N-dimethylaminophenyl)(dimethyl)silylmethyl](cycloocta-1,5-diene)platinum(II)
• CAS: 164856-06-8
• 化学式: C₃₀H₄₈N₂PtSi₂
• 分子量: 687.976
• InChiKey: FWKQOXIELDNRMN-KEUNEWJHSA-N

反应信息

• 作为反应物：
  描述：

  bis-[(4-N,N-dimethylaminophenyl)(dimethyl)silylmethyl](cycloocta-1,5-diene)platinum(II) 、 三苯基膦 以 乙醚 为溶剂， 以78%的产率得到cis-bis-[(4-N,N-dimethylaminophenyl)(dimethyl)silylmethyl]-bis-(triphenylphosphine)platinum(II)
  参考文献：
  名称：

  Syntheses and spectroscopic characteristics of bis-[dimethyl(aryl)silylmethyl]-platinum(II) and bis-[dimethyl(benzyl)-silylmethyl]platinum(II) complexes with diene-, nitrogen-, and phosphorus-donor ligands

  摘要：

  The preparations and spectroscopic characteristics of a range of aromatic ring-substituted aryl(dimethyl) silylmethyl (sila-neophyl) complexes of platinum(II) with diene-, nitrogen-, and phosphorus-donor ancillary ligands, cis-Pt(CH(2)SiMe(2)C(6)H(4)R)(2)L(2) (R = H, 2-Me, 3-Me, 4-Me, 4-OMe, 4-(t)Bu, 4-F, 2-CF3, 3-CF3, 4-CF3, 4-NMe(2)) and cis-Pt(CH2Si Me(2)C(6)F(5))(2)L(2) [L = PPh(3), pyridine (py); L(2) = cycloocta-1,5-diene (cod), bicyclo[2.2.1] hepta-2,5-diene (nbd)] are reported. Corresponding characteristics for benzylsilylmethylplatinum analogues, cis-Pt(CH(2)SiMe(2)CH(2)C(6)H(4)R)(2)L(2), (R = H, 4-Me; L(2) = cod; L = PPh(3)) are also presented.

  DOI：

  10.1016/0277-5387(94)00193-i
• 作为产物：
  描述：

  dichloro( 1,5-cyclooctadiene)platinum(ll) 、 4-{[(chloromagnesio)methyl]dimethylsilyl}-N,N-dimethylbenzenamine 以85%的产率得到bis-[(4-N,N-dimethylaminophenyl)(dimethyl)silylmethyl](cycloocta-1,5-diene)platinum(II)
  参考文献：
  名称：

  Syntheses and spectroscopic characteristics of bis-[dimethyl(aryl)silylmethyl]-platinum(II) and bis-[dimethyl(benzyl)-silylmethyl]platinum(II) complexes with diene-, nitrogen-, and phosphorus-donor ligands

  摘要：

  The preparations and spectroscopic characteristics of a range of aromatic ring-substituted aryl(dimethyl) silylmethyl (sila-neophyl) complexes of platinum(II) with diene-, nitrogen-, and phosphorus-donor ancillary ligands, cis-Pt(CH(2)SiMe(2)C(6)H(4)R)(2)L(2) (R = H, 2-Me, 3-Me, 4-Me, 4-OMe, 4-(t)Bu, 4-F, 2-CF3, 3-CF3, 4-CF3, 4-NMe(2)) and cis-Pt(CH2Si Me(2)C(6)F(5))(2)L(2) [L = PPh(3), pyridine (py); L(2) = cycloocta-1,5-diene (cod), bicyclo[2.2.1] hepta-2,5-diene (nbd)] are reported. Corresponding characteristics for benzylsilylmethylplatinum analogues, cis-Pt(CH(2)SiMe(2)CH(2)C(6)H(4)R)(2)L(2), (R = H, 4-Me; L(2) = cod; L = PPh(3)) are also presented.

  DOI：

  10.1016/0277-5387(94)00193-i