| 173413-68-8

• CAS: 173413-68-8
• 化学式: C₁₇H₂₃ClNO₂Rh
• 分子量: 411.734
• InChiKey: ZCHRBVIYNZFVEV-UHFFFAOYSA-L

反应信息

• 作为产物：
  描述：

  dichloro(pentamethylcyclopentadienyl)rhodium (III) dimer 、 sodium methylate 、 3-hydroxy-2-ethyl-4-pyridinone 以 甲醇 为溶剂， 以70%的产率得到
  参考文献：
  名称：

  Complexes of Rh(C5Me5) with picolinic acid, pyrones and pyridinones

  摘要：

  Picolinic acid (pyridine-2-carboxylic acid), pyrones and pyridinones (HL) reacted with [{Rh(C(5)Me(5))Cl-2}(2)] and sodium methoxide to give complexes [Rh(C(3)Me(5))Cl(L)] which are all soluble in water. The structures where HL = picolinic acid or 2-methylpyran-4-one have been determined by X-ray diffraction. The aquation of the complexes when dissolved in water has been examined by NMR spectroscopy and conductivity measurements and the results indicate an equilibrium between chloro and aqua species which is fast on the NMR time-scale.

  DOI：

  10.1039/dt9950003709