[bis(o-(diphenylphosphino)benzyl)methylsilyl]platinum(II)chloride | 174739-10-7

• 英文名称: [bis(o-(diphenylphosphino)benzyl)methylsilyl]platinum(II)chloride
• CAS: 174739-10-7
• 化学式: C₃₉H₃₅ClP₂PtSi
• 分子量: 824.273
• InChiKey: UUOAVGKZSASXPE-UHFFFAOYSA-M

反应信息

• 作为产物：
  描述：

  dichloro( 1,5-cyclooctadiene)platinum(ll) 、 bis(o-(diphenylphosphino)benzyl)methylsilane 在 三乙胺 作用下， 以 苯 为溶剂， 以27%的产率得到[bis(o-(diphenylphosphino)benzyl)methylsilyl]platinum(II)chloride
  参考文献：
  名称：

  （膦烷基）硅烷。3.（1）聚（邻-（二苯基膦基）苄基）硅烷：铂或铱的合成，光谱性质和络合

  摘要：

  Phosphino alkylsilanes in which Si is connected to P through a benzylic framework have been synthesized and used as precursors to chelate ligand systems which attach to transition metal centers through a silicon-metal bond supported by one, two, or three intramolecular phosphorus-metal bonds. The resulting stereochemistry around Ir(III) in IrH(mctriPSi)Cl (7), in which quadridentate coordination of the mctriPSi ligand cage leads to occupation of four adjacent octahedral sites with H trans to P and Cl trans to Si, is assigned using multinuclear NMR spectroscopy.

  DOI：

  10.1021/ic941230f