| 167287-07-2

• CAS: 167287-07-2
• 化学式: C₁₁H₈ClN₂O₂Rh
• 分子量: 338.555
• InChiKey: CGDUMMYUNXFGEY-UHFFFAOYSA-M

反应信息

• 作为产物：
  描述：

  Rh⁽¹⁺⁾*Cl^(1-)*C₇H₈*C₃H₃N₂C₆H₅*0.25CH₂Cl₂=[RhCl(C₇H₈)(C₃H₃N₂C₆H₅)]*0.25CH₂Cl₂ 、 一氧化碳 以 二氯甲烷 为溶剂， 以99%的产率得到
  参考文献：
  名称：

  Bulky pyrazole as ligands in rhodium(I) complexes. Crystal structure of chlorodicarbonyl (3-p-methoxyphenylpyrazole)rhodium(I)

  摘要：

  A new family of complexes containing bulky pyrazoles substituted in the 3 or the 3 and 5 positions, [RhCl(L(2))(Hpz(R',R''))] (L(2) = NBD, 2CO; R' = Bu(t), Ph, p-CH3OC6H4 (An), R'' = H; R' = Bu(t), Ph, R'' = CH3; R' = R'' = H, CH3), has been obtained. A dynamic behaviour has been observed only in complexes with the less demanding pyrazole ligands, relating with a metallotropic equilibrium when R' = R'' = H, Me, or a diolefin reorientation when R' = Bu(t), Ph, An, R'' = H. The X-ray crystal structure of [RhCl(CO)(2)(Hpz(An))] has been solved, showing a molecular stacking with a Rh-Rh separation of 3.398(3) Angstrom along the one-dimensional chain.

  DOI：

  10.1016/0277-5387(94)00382-o