(η(5)-C5Me5)(CO)(2,6-Me2C6H3NC)FeP=C(NMe2)2 | 190784-70-4

• 英文名称: (η(5)-C5Me5)(CO)(2,6-Me2C6H3NC)FeP=C(NMe2)2
• CAS: 190784-70-4
• 化学式: C₂₅H₃₆FeN₃OP
• 分子量: 481.401
• InChiKey: MIUIMOFZPNIULW-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  ((η(5)-C5Me5)(CO)2FeP=C(NMe2)2) 、 2,6-二甲基苯基异腈 以 正戊烷 为溶剂， 以36%的产率得到(η(5)-C5Me5)(CO)(2,6-Me2C6H3NC)FeP=C(NMe2)2
  参考文献：
  名称：

  过渡金属取代的磷烯烃和酰基膦。二十九。Metallophosphaalkene（η 5 -C 5我5）（CO）2 FEPC（NME 2）2，一种多功能分子配位化学

  摘要：

  所述metallophosphaalkene（η 5 -C 5我5）（CO）2 FEPC（NME 2）2（2）经历与异氰化物，得到配合物反应（η 5 ç 5我5）（CO）（RNC）FEPC（NME 2）2（4a：R ＝ 2.6-Me 2 C 6 H 3；4b：t Bu：4c：c -C 6 H 11）。化合物2转化为其[[CO）3倪] -adduct（η 5 -C 5我5）（CO）2 FEP [镍（CO）3 ] C（NME 2）2（5）通过暴露于的Ni（CO）4。与此相反，一个环甲基的缩合反应过程中，观察到2与[（ż）-cyclooctene]的Cr（CO）5，得到η 5 -C 5我4 CHC（NME 2）PH [CR（CO）5 ] Fe（CO）2（8）。辐照2和Fe 2（CO）的等摩尔混合物9种配料复杂η 2 - （C，P）[η 5 -C 5我5）（CO）2 FEP [C（O）NME 2 ]

  DOI：

  10.1016/s0022-328x(96)06461-3

文献信息

• Metallophosphaalkenes—from Exotics to Versatile Building Blocks in Preparative Chemistry
  作者：Lothar Weber

  DOI：10.1002/anie.199602711

  日期：1996.2.16

  AbstractThe chemistry of low‐valent organophosphorus compounds such as phosphaalkenes and phosphaalkynes has undergone rapid development in the last two decades. This development also includes the coordination chemistry of these species, which can act as versatile ligands in metal complexes. Metallophosphaalkenes are compounds in which one or more of the organic substituents on the PC unit is replaced by a transition metal complex fragment. Metallophosphaalkenes have emerged from an existence as laboratory curiosities to become a link between main group and organometallic complex chemistry. The great richness of their chemistry not only mirrors the specific properties of the individual building block, but also shows novel and individual traits. Particular examples are cycloadditions of these electron‐rich heteroalkenes with electron‐deficient alkenes, alkynes, azo, and diazo compounds. These often lead to novel types of reaction and compounds. Metallophosphaalkenes are also important as intermediates in all metal‐assisted cyclooligomerizations of phosphaalkynes.