[(η5-pentamethylcyclopentadienyl)(ruthenium)(PPh3))(4,4'-bis(2-pyridyl-4-thiazole)](hexafluorophosphate) | 1210606-09-9

• 英文名称: [(η5-pentamethylcyclopentadienyl)(ruthenium)(PPh3))(4,4'-bis(2-pyridyl-4-thiazole)](hexafluorophosphate)
• CAS: 1210606-09-9
• 化学式: C₄₄H₄₀N₄PRuS₂*F₆P
• 分子量: 965.968
• InChiKey: YHWVIQRNCKEOAT-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  六氟磷酸钾 、 五甲基环戊二烯基双(三苯基膦)氯化钌(II) 、 [4,4'-bis(2-pyridyl-4-thiazole)] 以 甲醇 为溶剂， 以79%的产率得到[(η5-pentamethylcyclopentadienyl)(ruthenium)(PPh3))(4,4'-bis(2-pyridyl-4-thiazole)](hexafluorophosphate)
  参考文献：
  名称：

  Mono and dinuclear complexes of half-sandwich platinum group metals (Ru, Rh and Ir) bearing a flexible pyridyl-thiazole multidentate donor ligand

  摘要：

  The mononuclear cationic complexes [(eta(6)-C6H6)RuCl(L)](+) (1), [(eta(6)-p-(PrC6H4Me)-Pr-i)RuCl(L)](+) (2), [(eta(5)-C5H5)Ru(PPh3)(L)](+) (3), [(eta(5)-C5Me5)Ru(PPh3)(L)](+) (4), [(eta(5)-C5Me5)RhCl(L)](+) (5), [(eta(5)-C5Me5)IrCl(L)](+) (6) as well as the dinuclear dicationic complexes [{(eta(6)-C6H6)RuCl}(2)(L)](2+) (7), [{(eta(6)-p-(PrC6H4Me)-Pr-i)RuCl}(2)(L)](2+) (8), [{(eta(5)-C5H5)Ru(PPh3)}(2)(L)](2+) (9), [{(eta(5)-C5Me5)Ru(PPh3)}(2)(L)](2+) (10), [{(eta(5)-C5Me5)RhCl}(2)(L)](2+) (11) and [{(eta(5)-C5Me5)IrCl}(2)(L)](2+) (12) have been synthesized from 4,4'-bis(2-pyridyl-4-thiazole) (L) and the corresponding complexes [(eta(6)-C6H6)Ru(mu-Cl)Cl](2), [(eta(6)-p-(PrC6H4Me)-Pr-i)Ru(mu-Cl)Cl]2, [(eta(5)-C5H5)Ru(PPh3)(2)Cl)], [(eta(5)-C5Me5)Ru(PPh3)(2)Cl], [(eta(5)-C5Me5)Rh(mu-Cl)Cl](2) and [(eta(5)-C5Me5)Ir(mu-Cl)Cl](2), respectively. All complexes were isolated as hexafluorophosphate salts and characterized by IR, NMR, mass spectrometry and UV-vis spectroscopy. The X-ray crystal structure analyses of [3]PF6, [5]PF6, [8](PF6)(2) and [12](PF6)(2) reveal a typical piano-stool geometry around the metal centers with a five-membered metallo-cycle in which 4,4'-bis(2-pyridyl-4-thiazole) acts as a N, N'-chelating ligand. (C) 2009 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2009.10.007