[MoCl(CO)2(η3-CH2C(CONHC16H23O6))CCH2)(1,10-phenanthroline)] | 762241-19-0

• 英文名称: [MoCl(CO)2(η3-CH2C(CONHC16H23O6))CCH2)(1,10-phenanthroline)]
• 英文别名: [MoCl(CO)2(η3-CH2C(CONHC16H23O6)CCH2)(phen)]
• CAS: 762241-19-0
• 化学式: C₃₅H₃₆ClMoN₃O₉
• 分子量: 774.079
• InChiKey: UCTDMVIOEPEDNS-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  MoCl(CO)2(1,10-phenanthroline)(η(3)-CH2C(COCl)C=CH2) 、 (苯并-18-冠-6)-4′-基胺 在 三乙胺 作用下， 以 二氯甲烷 为溶剂， 生成 [MoCl(CO)2(η3-CH2C(CONHC16H23O6))CCH2)(1,10-phenanthroline)]
  参考文献：
  名称：

  Substituent control of selective alkali metal ion extraction by amidocrown η3-butadienyl complexes of molybdenum(II)

  摘要：

  Substituted eta(3)-butadienyl complexes containing amide-armed crowns (X) of general formula [MoCl(CO)(2)(eta(3)-CH2C(COX)-C=CH2)(phen)](n) (phen = 1,10-phenanthroline) were prepared and investigated for their ability to extract alkali metal ions from a mixed phase system. Reaction of the chlorocarbonyl precursor (1) with 1-aza-15-crown-5, 4'-aminobenzo-15-crown-5, 2-aminomethyl- 15-crown-5, 4'-aminobenzo-18-crown-6 or 2-aminomethyl-18-crown-6 gave monomeric complexes (n = 1), and addition of sodium tetraphenylboron to the 15-crown-5-substituted complexes gave the corresponding sodium salts. Dinuclear complexes (n = 2) were formed by reaction of 1 and 1,7-diaza-15-crown-5 or 4,4'(5)-diaminobenzo-15-crown-5. Comparison of amidobenzo- and 2-amidomethyl-15-crown-5-substituted complexes showed enhanced sodium transport properties for the latter, and spectroscopic and molecular modeling studies suggested complexation occurred by concerted action of the amide and crown. (C) 2004 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2004.01.046