| 197776-91-3

• CAS: 197776-91-3
• 化学式: C₈H₁₄Cl₂IrP
• 分子量: 404.299
• InChiKey: ZEYMJOHAVGKMAM-UHFFFAOYSA-L

反应信息

• 作为反应物：
  描述：

  、 以 N,N-二甲基甲酰胺 为溶剂， 以79%的产率得到
  参考文献：
  名称：

  Reaction of halfsandwich iridium polychalcogenide complexes with dimethyl acetylenedicarboxylate. Molecular structure of Cp*Ir[S2C2(COOMe)2]

  摘要：

  The pentamethylcyclopentadienyl iridium complexes Cp*Ir(PMe3)(En) (E=S, n=4, 5 or 6; E=Se, n=2 or 4; E=Te, n=2) react with dimethyl acetylenedicarboxylate to give Cp*Ir(PMe3)[E2C2(COOMe)2] compounds which tend to lose the trimethylphosphine ligand; the molecular structure of the dithiolene derivative, Cp*Ir[S2C2(COOMe)2], has been determined.

  DOI：

  10.1039/a806085a