| 211317-79-2

• CAS: 211317-79-2
• 化学式: C₃₈H₃₃FeNP₂S₂*F₆P
• 分子量: 830.577
• InChiKey: KGAFFQKWBCVXBQ-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
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• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  ammonium hexafluorophosphate 、 [1,2-bis(diphenylphosphino)ethane](η5-cyclopentadienyl)iron(II) iodide 、 二硫化二苯并噻唑 以 甲醇 为溶剂， 以57%的产率得到
  参考文献：
  名称：

  Redox properties of 17-electron thiolate complexes of cyclopentadienyl iron (III)

  摘要：

  The redox electrochemistry of iron (III) thiolate complexes of the type [CpFe(dppe)-SR]PF6 R = CH3, C3K7, C6H5, p-C6H4Br and thiobenzothiazole has been examined by cyclic voltammetry, coulometry and spectroelectrochemistry methods. Four redox waves were observed in the range - 1.5 to + 1.5 V (S.C.E) in CH2Cl2. Around 0.0 V the-metal centered reduction Fe (III)-->Fe(II) process was observed, while that around +0.5V the wave observed was attributed to a ligand centered oxidation. Strongly irreversible waves of oxidation near 1.3 V were assigned to the oxidation of RSSR while a reduction wave also strongly irreversible at very high negative potential was attributed to the reduction of the RSSR free ligand, RSSR+2e-->2RS(-). The redox wave observed for the disulphides compounds are discussed in terms of a reductive elimination of RSSR. Chemical and electrochemical reduction of the complexes [CpFe(dppe)-SR]PF6 was accomplished by the color changes blue --> red-brown characteristic of the redox change 17e-->18e. (C) 1998 Elsevier Science Ltd. Al rights reserved.

  DOI：

  10.1016/s0277-5387(98)00054-0