[1,3-dimethyl-2-(phenylazo)imidazolium][N,N-dimethylammonium][zinc(chloride)4] | 1239449-12-7

• 英文名称: [1,3-dimethyl-2-(phenylazo)imidazolium][N,N-dimethylammonium][zinc(chloride)4]
• 英文别名: [HaaiMe2][Me2NH2][ZnCl4]
• CAS: 1239449-12-7
• 化学式: C₂H₈N*C₁₁H₁₃N₄*Cl₄Zn
• 分子量: 454.545
• InChiKey: VUVKNEUKGPGRNN-UHFFFAOYSA-K

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  [1,3-dimethyl-2-(phenylazo)imidazolium]2[zinc(chloride)4] 、 水 、 N,N-二甲基甲酰胺 以 甲醇 为溶剂， 生成 [1,3-dimethyl-2-(phenylazo)imidazolium][N,N-dimethylammonium][zinc(chloride)4]
  参考文献：
  名称：

  Arylazoimidazoliumchloride and chlorometallates: Spectroscopic and structural characterization

  摘要：

  Protonation or dialkylation of 2-(arylazo)imidazoles (RaaiH) has generated azoimidazolium motif (RaaiH(2)(+), RaaiR'H+, RaaiR(2)'(+) where R = H, CH3 and R' = Me, Et, -CH2Ph). Electrostatic attraction between imdazolium cation and counter ions like Cl, ZnCl42-, PtCl62- has generated hydrogen bonded azoimidazolium-chloride/chlorometallated networks. The single crystal X-ray structure of 1-benzyl-2-(phenylazo) imidazolium chloride shows tape like 1-D network of [Cl(H2O)(4)]. Aquated Cl forms 10 membered supracycle through hydrogen bonding with imidazolium ion. The X-ray structures of [HaaiMe(2) (1,3)](+)[Me2NH2](+) [ZnCl4](2) and [MeaaiH(2)(+)center dot H2O](2)[PtCl6](2) show hydrogen bonded chlorometallate chain penetrated into the channel developed by organic motif. Azoimidazolium units are associated through pi center dot center dot center dot pi and C-H center dot center dot center dot pi interactions to strengthen the supramolecular geometry. (C) 2010 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2010.02.006