[Cu(1-(N-salicylideneimino)-2-(N,N-diethyl)aminoethane)(N3)] | 120771-62-2

• 英文名称: [Cu(1-(N-salicylideneimino)-2-(N,N-diethyl)aminoethane)(N3)]
• 英文别名: [Cu(1-(N-salicylideneimino)-2-(N,N-diethyl)aminoethane)(N₃)]；[copper(II) (1-(N-salicylideneimino)-2-(N,N-diethyl)-aminoethane(1-)) (azide)]
• CAS: 120771-62-2
• 化学式: C₁₃H₁₉CuN₅O
• 分子量: 324.873
• InChiKey: RQVVQGWICJRJIK-IVKCLRODSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  [Cu(1-(N-salicylideneimino)-2-(N,N-diethyl)aminoethane)(N3)] 以 水 、 丙酮 为溶剂， 生成 (N-(2-(diethylamino)ethyl)salicylaldimine)Cu(II)(H2O)(1+)
  参考文献：
  名称：

  Röper, Jürgen R.; Paulus, Helmut; Elias, Horst, Inorganic Chemistry, 1989, vol. 28, # 12, p. 2323 - 2329

  摘要：

  DOI：
• 作为产物：
  描述：

  、 sodium azide 以 乙醇 为溶剂， 以90%的产率得到[Cu(1-(N-salicylideneimino)-2-(N,N-diethyl)aminoethane)(N3)]
  参考文献：
  名称：

  Röper, Jürgen R.; Paulus, Helmut; Elias, Horst, Inorganic Chemistry, 1989, vol. 28, # 12, p. 2323 - 2329

  摘要：

  DOI：

文献信息

• Synthesis, characterization, X-ray structure and magnetic study of the azido adducts of tridentate (NNO) Schiff base copper (II) complexes
  作者：Chandan Adhikary、Dasarath Mal、Ken-Ichi Okamoto、Siddhartha Chaudhuri、Subratanath Koner

  DOI：10.1016/j.poly.2006.01.011

  日期：2006.7

  Two new azido derivatives of tridentate Schiff base copper (II) complexes have been synthesized and characterized. X-ray single crystal structure analysis reveals that the complex [Cu(L1)(N-3)] (1), containing 1-(N-salicylideneimino)-2-(N,N-diethyl)-aminoethane (HL1) as co-ligand, is monomeric in nature while complex [Cu(L2)(N3)](n) (2), containing 1-(N-salicylideneimino)-2-(N,N-dimethyl)-aminoethane (HL2) as co-ligand, has a one-dimensional infinite chain structure in which copper (II) ions are bridged by single azido groups in end-to-end fashion. The co-ordination environment around copper (II) is square planar in the case of complex (1); of the four co-ordination sites, three are occupied by the two nitrogen atoms and the oxygen atom of the tridentate Schiff base ligand (HL1) and the fourth site is occupied by an azido group. On the other hand, in complex (2), the copper (II) co-ordination is distorted square pyramidal. The four in-plane co-ordination sites are similar to those in complex (1). The fifth apical coordination is provided by a nitrogen atom of the azido group of a symmetry related moiety with a long Cu-N bond distance, resulting in the polymerization of the complex. The variable temperature magnetic susceptibility measurements showed that the magnetic interaction in [Cu(L2)(N3)](n) (2) is antiferromagnetic (J= -22.5(+/- 0.2) cm(-1)) while as expected the complex [Cu(L1)(N-3)] (1) is paramagnetic. The solution electronic spectra of the complexes show strong absorption bands associated with N-3(-) --> Cu(II) charge transfer transitions. (C) 2006 Elsevier Ltd. All rights reserved.