RuCl(CO)2(2,6-(Ph2PCH2)2C6H3) | 192751-55-6

• 英文名称: RuCl(CO)2(2,6-(Ph2PCH2)2C6H3)
• CAS: 192751-55-6
• 化学式: C₃₄H₂₇ClO₂P₂Ru
• 分子量: 666.058
• InChiKey: GWOBYCHQQGDSPG-UHFFFAOYSA-M

反应信息

• 作为产物：
  描述：

  [1,3-(Ph2PCH2)2C6H3-2-Ru(Cl)PPh3] 、 一氧化碳 以 二氯甲烷 为溶剂， 以91%的产率得到RuCl(CO)2(2,6-(Ph2PCH2)2C6H3)
  参考文献：
  名称：

  Five- and six-coordinate ruthenium complexes with the tridentate orthometallated aryl bisphosphine ligand [2,6-(Ph2PCH2)2C6H3]−

  摘要：

  A series of ruthenium complexes with the orthometallated ligand [2,6-(Ph2PCH2)(2)C6H3](-) (PCP) was synthesized. Reaction of RuCl2(PPh3)(3) with 1,3-(Ph2PCH2)(2)C6H4 produced the coordinatively unsaturated complex RuCl(PPh3)(PCP), which was characterized by X-ray crystallography. Treatment of RuCl(PPh3)(PCP) with 4-phenylpyridine (pyph) yielded RuCl(pyph)(PPh3)(PCP). Treatment of RuCl(PPh3)(PCP) with PMe3 and CO generated RuCl(PMe3)(2)(PCP) and RuCl(CO)(2)(PCP) respectively. Reactions of RuCl(PPh3)(PCP) with NaH in THF and NaBH4 in methanol gave RuH(PPh3)(PCP) and RuH(CO)(PPh3)(PCP) respectively. The hydride complex RuH(PMe3),(PCP) was prepared by the reaction of RuCl(PMe3),(PCP) with NaBH4.

  DOI：

  10.1016/s0022-328x(96)06926-4