[Pd([(η5-C5H3)-CH=N-(C6H4-2-SMe)]Fe(η5-C5H5))(triphenylphosphine)Cl] | 790689-40-6

• 英文名称: [Pd([(η5-C5H3)-CH=N-(C6H4-2-SMe)]Fe(η5-C5H5))(triphenylphosphine)Cl]
• CAS: 790689-40-6
• 化学式: C₃₆H₃₁ClFeNPPdS
• 分子量: 738.409
• InChiKey: NEFRFZQAUOUEHJ-BNNCHDLHSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  [Pd(((η5-C5H3)CH=N(C6H4-2-SMe))Fe(η5-C5H5))Cl] 、 三苯基膦 以 苯 为溶剂， 以87%的产率得到[Pd([(η5-C5H3)-CH=N-(C6H4-2-SMe)]Fe(η5-C5H5))(triphenylphosphine)Cl]
  参考文献：
  名称：

  Factors affecting the lability of the σ(M–X) bond in cycloplatinated and cyclopalladated complexes containing [C(sp2, ferrocene),N,X]− or [C(sp2, phenyl),N,X]− (X=S, N) terdentate ligands

  摘要：

  The reactions of the cyclometallated complexes [M {[(n(5)-C5H3)-CH=N-(C6H4-2-SMe)]Fe(n(5)-C5H5)}Cl] [with M = Pt (5a) or Pd (5b)] with PPh3 under different experimental conditions are reported.These studies have allowed the isolation of [M{[(eta(5)- C5H3)-CH=N-C6H4-2-SMe]Fe(eta(5)-C5H5)}(PPh3)]X [M = Pt and X- = Cl- (6a) or BF4- (7a) or M = Pd and X- = Cl- (6b) or BF4- (7b)] and the neutral complex [Pd{[eta(5)-C5H3)-CH=N-(C6H4-2-SMe)]Fe(eta(5)-C5H5)}Cl(PPh3)] (8b). In 6-7a,b the ferrocenyl Schiff base behaves as a [C(sp(2), ferrocene),N,S](-) group while in 8b it acts as a [C(SP2, ferrocene),N](-) ligand. The X-ray crystal structure of 7b confirms the mode of binding of the ferrocenyl ligand.The comparison of the results obtained and those reported for [M{(C6H4)-CH=N-(CH2-CH2-2-SEt)}Cl] and [M{(C6H4)-CH=N-(C6H4-2-SMe)Cl] {with a [C(SP2, phenyl),N,S](-) terdentate ligand} or [M{eta(5)-C5H3)-CH=N-(CH2)(3)-NMe2]Fe(eta(5)-C5H5)}Cl] {in which the ligand acts as a [C(sp(2), ferrocene),N,N'](-) group} have allowed the elucidation of the relative importance of the factors affecting the lability of the M-X (X = S or N') and M-Cl bonds in cyclometallated compounds with [C,N,S](-) and [C(sp(2), ferrocene),N,X](-) ligands. (C) 2004 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2004.07.007