[InCl(2,6-(Me2NCH2)2C6H3)]2 | 211449-45-5

• 英文名称: [InCl(2,6-(Me2NCH2)2C6H3)]2
• CAS: 211449-45-5
• 化学式: C₂₄H₃₈Cl₂In₂N₄
• 分子量: 683.139
• InChiKey: WYAVHOOYTPUKHR-UHFFFAOYSA-L

反应信息

• 作为产物：
  描述：

  InCl2(2,6-(Me2NCH2)2C6H3) 在 Li₂(C₄H₄BN(i-Pr)2) 作用下， 以 四氢呋喃 为溶剂， 以24.9%的产率得到[InCl(2,6-(Me2NCH2)2C6H3)]2
  参考文献：
  名称：

  An indium(II)-indium(II) compound with intramolecular donor-acceptor bonds

  摘要：

  The diindium compound {2,6-(Me2NCH2)(2)C6H3} (Cl)In - In(Cl) {(2,6-Me2NCH2)(2)C6H3} (2) has been prepared via the reaction of [(2,6-Me2NCH2)(2)C6H4]InCl2 with Li-2[(C4H4BN(Pr-i)(2)]. By means of X-ray crystallography, it was established that four N --> In donor-acceptor bonds are made to the unsuspended In-In moiety: monoclinic, space group C-2/c, with a = 21.913 (6), b = 8.364 (1), c = 17.877 (3) Angstrom, alpha = 90, beta = 117.21 (2), gamma = 90 degrees, V = 2914 (1) Angstrom(3) and Z = 4. (C) 1998 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0022-328x(98)00364-7