1,1'-bis(2,6-dithia-1-phosphanyl)ferrocene | 185335-29-9

• 英文名称: 1,1'-bis(2,6-dithia-1-phosphanyl)ferrocene
• CAS: 185335-29-9
• 化学式: C₁₆H₂₀FeP₂S₄
• 分子量: 458.393
• InChiKey: GDNRKZZTMSZHGU-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  1,3-丙二硫醇 、 1,1'-bis(dichlorophosphino)ferrocene 在 Et₃N 作用下， 以 乙醚 为溶剂， 以47%的产率得到1,1'-bis(2,6-dithia-1-phosphanyl)ferrocene
  参考文献：
  名称：

  New potentially cytotoxic thiolatogold(I) complexes of 1,1′-bis(diphenylphosphino)ferrocene

  摘要：

  1,1'-Bis[chlorogold(I) diphenylphosphino] ferrocene (1) was chosen as the starting material to synthesize new thiolato gold(I) complexes. This has been achieved by substituting the chlorine atoms by monofunctional and bifunctional thiolates affording 'open' thiolatogold complexes and trimetallic ferrocenophane-type structures, respectively. The new 1,1'-bis(2,6-dithia-1-phosphanyl)ferrocene (7) containing directly linked P and S atoms was also prepared but no gold complex was obtained. Compound 2 crystallizes in the monoclinic space group P2(1)/n with a=10.263(2), b=21.064(4), c=16.259(3) Angstrom, beta=97.06(2)degrees and V=3.488(1) Angstrom(3). The distance between the two gold atoms (3.06 A) indicates a significant contact interaction. Compounds 2-5 have allowed antitumoral efficiency on human bladder and colon carcinoma.

  DOI：

  10.1016/s0020-1693(96)05111-0