[mer-Mn(CO)3(η2-dpm)Cl]tetrafluoroborate | 246137-67-7

• 英文名称: [mer-Mn(CO)3(η2-dpm)Cl]tetrafluoroborate
• CAS: 246137-67-7
• 化学式: BF₄*C₂₈H₂₂ClMnO₃P₂
• 分子量: 645.624
• InChiKey: BIUSVGLEOMHVLY-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  fac-{manganese(Cl)(carbonyl)3(dppm)} 、 nitrosonium tetrafluoroborate 以 二氯甲烷 为溶剂， 生成 [mer-Mn(CO)3(η2-dpm)Cl]tetrafluoroborate
  参考文献：
  名称：

  Photocatalytic Reactions at Microcrystalline fac-Mn(CO)₃(η²-Ph₂PCH₂PPh₂)Cl−Electrode−Aqueous (Electrolyte) Interfaces

  摘要：

  The electrochemical oxidation of fac-Mn(CO)(3)(eta(2)-dpm)Cl (dpm = Ph2PCH2PPh2) is extensively photocatalyzed when a microcrystal - electrode - aqueous (electrolyte) interface is irradiated with light having a wavelength corresponding to that of the 385 nm charge-transfer band. Investigations of the voltammetry of the solid in the presence and absence of light and monitoring the course of the reaction by EPR, electron probe, and electrochemical quartz crystal microbalance techniques indicate that the catalysis is associated with enhanced charge transport caused by doping of fac-Mn(CO)(3)(eta(2)-dpm)Cl with photooxidized mer-[Mn(CO)(3)(eta(2)-dpm)Cl]X, where the anion, X-, is incorporated into the solid after mass transport from the aqueous electrolyte. Photocatalysis also is found for the electrochemical oxidation of cis,mer-Mn(CO)(2)(eta(1)-dpm)(eta(2)-dpm)Br.

  DOI：

  10.1021/ja9908974