[(Cu(μ-N=C(Bu(t))Ph))4(PPh3)2] | 168099-77-2

• 英文名称: [(Cu(μ-N=C(Bu(t))Ph))4(PPh3)2]
• CAS: 168099-77-2
• 化学式: C₈₀H₈₆Cu₄N₄P₂
• 分子量: 1419.72
• InChiKey: GDUOAHBHZINZBG-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  copper(l) chloride 、 Sn[μ-N=C(Bu(t))Ph]3Li * tetrahydrofuran 在 triphenylphosphine 作用下， 以 四氢呋喃 为溶剂， 以63%的产率得到[(Cu(μ-N=C(Bu(t))Ph))4(PPh3)2]
  参考文献：
  名称：

  Ligand transfer from a tris(imino)stannate anion; syntheses and structures of [{Cu[µ-NC(Bu^t)Ph]}₄]·thf(thf = tetrahydrofuran) and [{Cu[µ- NC(Bu^t)Ph]}₄(PPh₃)₂]·6thf

  摘要：

  The Group 11 metal imino complexes [{Cu[mu-N = C(BUt)Ph]}(4)]. thf 2 (thf = tetrahydrofuran) and [{CU[mu-N=C(BUt)Ph]}(4)(PPh(3))(2)]. 6thf 3 have been prepared by the unusual ligand-transfer reactions of the tris(imino)stannate complex Sn[mu-N = C(BUt)Ph]Li-3 . thf with CuCl; both complexes have been shown by crystallography to contain planar Cu-4 cores.

  DOI：

  10.1039/dt9950002707