[(Me₃SiN=PPh₂)₂(GeCl)CMn(μ-Cl)]₂ | 1428471-64-0

• 英文名称: [(Me₃SiN=PPh₂)₂(GeCl)CMn(μ-Cl)]₂
• CAS: 1428471-64-0
• 化学式: C₆₂H₇₆Cl₄Ge₂Mn₂N₄P₄Si₄
• 分子量: 1510.42
• InChiKey: PAXBKVKDTYJDOX-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  [(Me3SiN=PPh2)2C=Ge→Ge=C(PPh2=NSiMe3)2] 、 manganese(ll) chloride 以 四氢呋喃 为溶剂， 反应 46.0h， 以35%的产率得到[(Me₃SiN=PPh₂)₂(GeCl)CMn(μ-Cl)]₂
  参考文献：
  名称：

  Synthesis of Hetero-Binuclear Complexes from Bisgermavinylidene

  摘要：

  Bisgermavinylidene [(Me3SiN=PPh2)(2)C=Ge -> Ge=C(PPh2=NSiMe3)(2)] (1) has been used as a source of unstable germavinylidene for the synthesis of a series of heterobinuclear complexes. The reaction of 1 with stoichiometric amounts of transition metal chlorides MCl2 (M = Mn, Fe) yielded [(Me3SiN=PPh2)(2)(GeCl)CMn(mu-Cl)](2) (2) and [(Me3SiN=PPh2)(2)(GeCl)CFeCl] (3), respectively. Treatment of 1 with Me3SiN3, gave the [2 + 3] cycloaddition product [(Me3SiN=PPh2)(2)CGeN(SiMe3)N=N] (4). While similar reaction of 1 with (Bu-n)(3)SnN3 (Bu-n = n-butyl) and water-borane adduct H2O -> B(C6F5)(3) afforded the 1,2-addition products [(Me3SiN=PPh2){(Bu-n)(3)Sn}CPPh2NSiMe3GeN3] (5) and [HC(PPh2=NSiMe3)(2)Ge(OH)B(C6F5)(3)] (6), respectively. The results suggested that the germanium-carbon bond in germavinylidene is capable of forming addition reaction products. The X-ray structures of 2-6 have been determined.

  DOI：

  10.1021/ic400056f