[2-(benzoylpyridine)-η2-C,O]bis(trimethylphosphine)nickel(0) | 1160931-48-5

• 英文名称: [2-(benzoylpyridine)-η2-C,O]bis(trimethylphosphine)nickel(0)
• CAS: 1160931-48-5
• 化学式: C₁₈H₂₇NNiOP₂
• 分子量: 394.056
• InChiKey: VLABCHGIMUXEFV-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  2-苯甲酰吡啶 、 NiMe2(PMe3)3 以 乙醚 、 正戊烷 为溶剂， 以57%的产率得到[2-(benzoylpyridine)-η2-C,O]bis(trimethylphosphine)nickel(0)
  参考文献：
  名称：

  Stabilization of dimethyliron(II) and methylcobalt(I) complexes bearing a hemilabile 2-benzoylpyridine ligand in octahedral and square-pyramidal coordination

  摘要：

  Octahedral cis-Fe(CH3)(2){2-(benzoyl)pyridyl-N,O}(PMe3)(2) (1), square-pyramidal Co(CH3){2-(benzoyl)pyridyl-N,O}(PMe3)(2) (2), and triangular- planar Ni{2-(benzoyl)pyridyl-eta(2)-C,O}(PMe3)(2) (3) have been synthesized by reaction of 2-benzoylpyridine with thermally labile Fe(CH3)(2)(PMe3)(4) and Co(CH3)(PMe3)(4) complexes. With Ni(CH3)(2)(PMe3)(3), reductive elimination of ethane is observed when a eta(2)-C, O-coordination is constituted. The complexes were investigated by NMR spectroscopic methods and the molecular structures of 1 and 2 were determined by X-ray crystallography. (c) 2008 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2008.09.021