[(η(5)-C5H4PPh2)2Yb(diethylene glycol dimethyl ether)] | 183056-62-4

• 英文名称: [(η(5)-C5H4PPh2)2Yb(diethylene glycol dimethyl ether)]
• CAS: 183056-62-4
• 化学式: C₄₀H₄₂O₃P₂Yb
• 分子量: 805.759
• InChiKey: YRZLIQGZYBRNPS-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  (diphenylphosphino)cyclopentadienylthallium 、 二乙二醇二甲醚 、 氢化镱 在 Hg 作用下， 以 四氢呋喃 为溶剂， 以40%的产率得到[(η(5)-C5H4PPh2)2Yb(diethylene glycol dimethyl ether)]
  参考文献：
  名称：

  Synthesis and structural characterization of functionalized organolanthanide complexes [(η5-C5H4PPh2)2Ln(DIME)] (Ln = Eu, Yb) (DIME = diethylene glycol dimethyl ether)

  摘要：

  The reaction of [(diphenylphosphino)cyclopentadienyl]thallium [Tl(C(5)H(4)PPh(2))] with metallic europium or ytterbium powder in THF (tetrahydrofuran) at 60 degrees C in the presence of metallic mercury, followed by crystallization from a mixture of dimethoxyethane and diethylene glycol dimethyl ether (DIME) (10:1), afforded [(eta(5)-C(5)H(4)PPh(2))(2)Eu(DIME)] 1 and [(eta(5)-C(5)H(4)PPh(2))(2)Yb(DIME)] 2 respectively. Crystal and molecular structures of 1 and 2 have been determined by X-ray crystallography.

  DOI：

  10.1016/0022-328x(96)06332-2