[(η5-C5Me5)(1,2-bis(diphenylphosphino)ethane)Fe(C=C(Ph)CH(CN))] | 929223-66-5

• 英文名称: [(η5-C5Me5)(1,2-bis(diphenylphosphino)ethane)Fe(C=C(Ph)CH(CN))]
• CAS: 929223-66-5
• 化学式: C₄₆H₄₅FeNP₂
• 分子量: 729.665
• InChiKey: LBTCVCWVCHEBQP-DBQHITQZSA-N

反应信息

• 作为产物：
  描述：

  [(η5-C5Me5)(1,2-bis(diphenylphosphino)ethane)Fe(=C=C(Ph)CH2CN)]I 在 四丁基氢氧化铵 作用下， 以 甲醇 、 丙酮 为溶剂， 以85%的产率得到[(η5-C5Me5)(1,2-bis(diphenylphosphino)ethane)Fe(C=C(Ph)CH(CN))]
  参考文献：
  名称：

  Deprotonation of Iron Vinylidene Complexes Containing a dppe Ligand

  摘要：

  Two iron complexes each containing a 1-ferra-2,5-diphospha-[2.1.1] ring are prepared by deprotonation reaction of cationic vinylidene complexes [Fe]CC(Ph)CH2R+ ([Fe] = (eta(5)-C5H5)(dppe)Fe, R = CHCH2 and Ph). The deprotonation takes place at the methylene proton of the dppe ligand, which is followed by an intramolecular addition giving the product. For similar vinylidene complexes with R = CN, p-C6H4CN, and p-C6H4CF3, the deprotonation reaction gave the cyclopropenyl complexes. The deprotonation of the vinylidene complex with R = C6F5 gave both the cyclopropenyl complex and the product containing a 1-ferra-2,5-diphospha-[2.1.1] ring system. The electron-withdrawing ability of the substituent near the C-gamma-methylene group of the vinylidene ligand determines the selectivity of deprotonation. Characterizations of vinylidene, cyclopropenyl complexes, and a complex containing a 1-ferra-2,5-diphospha-[2.1.1] ring are carried out using single-crystal X-ray diffraction analysis.

  DOI：

  10.1021/om061005t