CuMn(tidf)(H₂O)₂(ClO₄)₂ | 180519-28-2

• 英文名称: CuMn(tidf)(H₂O)₂(ClO₄)₂
• CAS: 180519-28-2
• 化学式: C₂₄H₃₀Cl₂CuMnN₄O₁₂
• 分子量: 755.912
• InChiKey: RIKKMQHNENPQEK-HJJXTPHTSA-J

反应信息

• 作为产物：
  描述：

  1,3-丙二胺 、 {N,N'-bis(3-formyl-5-methylsalicylidene)propane-1,3-diaminato}copper(II) 、 manganese(II) perchlorate hexahydrate 以 甲醇 为溶剂， 反应 12.0h， 以61%的产率得到CuMn(tidf)(H₂O)₂(ClO₄)₂
  参考文献：
  名称：

  Crystallographic evidence of metal scrambling in an N4O2-tetraiminodiphenolate macrocyclic complex

  摘要：

  Heterodinuclear complexes [CuZn(tidf)(H20)2(CI04)21 and [CuMn(tidf)(H20)2(C104)21 undergo intermolecular metal scrambling in water and water/acetonitrile solutions. X-ray diffraction, EPR and molecular magnetism unambiguously established the prominent species in solution and in the solid state. Spectroscopy properties in solution were in accordance with the presence of heterodinuclear complexes, while single-crystal determination revealed co-crystallization of homometallic COCO and MIIMII (M=Zn or Mn) macrocyclic complexes. (C) 2014 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.molstruc.2014.04.057