| 1443675-51-1

• CAS: 1443675-51-1
• 化学式: CH₄O*C₂₈H₃₃Cl₂FeN₃S
• 分子量: 602.451
• InChiKey: HQXVPEXSWMOOHC-HELXCDCQSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  、 氧气 以 二氯甲烷 为溶剂， 反应 96.0h， 生成
  参考文献：
  名称：

  Sulfide oxidation by O2: Synthesis, structure and reactivity of novel sulfide-incorporated Fe(II) bis(imino)pyridine complexes

  摘要：

  The unsymmetrical iron(II) bis(imino)pyridine complexes [Fe-II(LN3SMe)(H2O)(3)](OTf)(2) (1), and [Fe-II(LN3SMe)Cl-2] (2) were synthesized and their reactivity with O-2 was examined. Complexes 1 and 2 were characterized by single crystal X-ray crystallography, LDI-MS, H-1 NMR and elemental analysis. The LN3SMe ligand was designed to incorporate a single sulfide donor and relies on the bis(imino)pyridine scaffold. This scaffold was selected for its ease of synthesis and its well-precedented ability to stabilize Fe(II) ions. Complexes 1 and 2 ware prepared via a metal-assisted template reaction from the unsymmetrical pyridyl ketone precursor 2-(O=CMe)-6-(2,6-(Pr-i(2)-C6H3N=CMe)-C5H3N. Reaction of 1 with O-2 was shown to afford the S-oxygenated sulfoxide complex [Fe(LN3S(O)Me)(OTf)](2+) (3), whereas compound 2, under the same reaction conditions, afforded the corresponding sulfone complex [Fe(LN3S(O-2)Me)Cl](2+) (4). (C) 2013 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2013.01.043