[1-carbonyl-1-(η(5)-cyclopentadienyl)-3-methyl-2,2-diphenyl-1-trimethylphosphine-3-trimethylphosphoranylidene-1-tungsta-2-phosphacyclopropane] hexafluorophosphate | 164987-09-1

• 英文名称: [1-carbonyl-1-(η(5)-cyclopentadienyl)-3-methyl-2,2-diphenyl-1-trimethylphosphine-3-trimethylphosphoranylidene-1-tungsta-2-phosphacyclopropane] hexafluorophosphate
• CAS: 164987-09-1
• 化学式: C₂₆H₃₆OP₃W*F₆P
• 分子量: 786.307
• InChiKey: WCAGEWHTPHOLBQ-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  [Cp(CO)PMe3W(η(2)-(=C(Me)PPh2))]PF6 、 三甲基膦 以 二氯甲烷 为溶剂， 以91%的产率得到[1-carbonyl-1-(η(5)-cyclopentadienyl)-3-methyl-2,2-diphenyl-1-trimethylphosphine-3-trimethylphosphoranylidene-1-tungsta-2-phosphacyclopropane] hexafluorophosphate
  参考文献：
  名称：

  Amphiphilie kationischer η2-phosphinocarbenkomplexe des wolframs

  摘要：

  eta(2)-Phosphinocarbene complexes of tungsten containing a trimethyl-phosphine ligand show an amphiphilic behavior. With the Lewis acid SMe(+) an electrophilic attack occurs at the metal-carbon double bond to give 1-tungsta-2-phospha-4-thia-bicyclo[1.1.0]butane complexes. On the contrary the Lewis base, PMe(3), adds at the carbene carbon atom to yield a cationic trimethylphosphoraneylidene complex. However, treatment of dicarbonyl(eta(5)-cyclopentadienyl)[eta(2)-(diphenylphosphino)methylcarbene]-tungsten-tetraphenylborate with the less nucleophilic triethylamine causes deprotonation at the methyl group providing dicarbonyl(eta(5)-cyclopentadienyl)-eta(2)-diphenylphosphinovinyltungsten.

  DOI：

  10.1016/0022-328x(94)05246-8