| 1001161-75-6

• CAS: 1001161-75-6
• 化学式: C₂₅H₃₇BrF₄P₂PtS
• 分子量: 782.56
• InChiKey: RAQHQDWHLMKQLH-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  铂(三乙基膦)4 、 以 四氢呋喃 为溶剂， 生成
  参考文献：
  名称：

  Reactivity of fluorinated thioether ligands of the type [C6H4Br-2-(CH2SRF)] towards transition metal complexes of the group 10

  摘要：

  The fluorinated thioether compounds [C6H4Br-2-(CH2SRF)] (SRF = SC6F5 (1), SC6F4-4-H (2), SC6H4-2-F (3), SC6H4-3-F (4), SC6H4-4-F (5)) were synthesized and the reactivity of (1) was explored with transition metal complexes of the group 10. The results obtained indicate that the reactivity of these ligands is strongly dependent on the oxidation state of the metal center on the complex. Thus, products of the coordination of Pd(II) and Pt(II) to the sulfur moiety were obtained and unequivocally characterized by single crystal X-ray diffraction analyses. While spectroscopic evidence indicates that reaction of the Pt(0) compound [Pt(PEt3)(3)] leads to the formation of C-Br activation products, it is worth noting that similar reactions with Ni(0) and Pd(0) compounds only afford complex mixtures that in most of the cases indicate desulfurization of the ligands and decomposition of the metallic starting materials. (C) 2007 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2007.05.056