| 113726-09-3

• CAS: 113726-09-3
• 化学式: C₁₇H₃₄NiO₂P₂
• 分子量: 391.093
• InChiKey: LKYIVWSCXGBJLJ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  在 CO 作用下， 以 正戊烷 为溶剂， 生成
  参考文献：
  名称：

  Bonrath, Werner; Poerschke, Klaus R.; Wilke, Guenther, Angewandte Chemie, 1988, vol. 100, p. 853 - 855

  摘要：

  DOI：

文献信息

• Synthesis and reactivity studies on alkyl–aryloxo complexes of nickel containing chelating diphosphines: cyclometallation and carbonylation reactions
  作者：J. Cámpora、J.A. López、C. Maya、P. Palma、E. Carmona、P. Valerga

  DOI：10.1016/s0022-328x(01)01323-7

  日期：2002.2

  Nickel alkyl-aryloxo complexes of composition Ni(R)(O-C(6)Hl(3)-2,6-Me-2)(P-P) (R=CH2SiMe3, CH3, CH2CMe2Ph; P-P =PPr'(2)(CH2)(n)PPr'(2), n=2 (dippe) or 3 (dippp)) have been synthesized. While the (trimethylsilyl)methyl and the methyl derivatives are stable in solution at room temperature, the bis-neophyl (R = CH2CMe2Ph) complexes undergo a cyclometallation reaction that leads to the metallacvcles N together with 2,6-dimethylphenol. The alkyl-aryloxo complexes cleanly react with carbon monoxide giving products resulting from CO insertion and reductive elimination, i.e. Ni(CO)(2)(P-P) and the corresponding 2.6-dimethylphenyl carboxylates quantitatively. (C) 2002 Elsevier Science B.V. All rights reserved.