[Mo2(η(5),η(5)-C8H4(1,4-Si(i)Pr3)2)] | 205809-61-6

• 英文名称: [Mo2(η(5),η(5)-C8H4(1,4-Si(i)Pr3)2)]
• CAS: 205809-61-6
• 化学式: C₅₂H₉₂Mo₂Si₄
• 分子量: 1021.52
• InChiKey: MDPYRSGNYYRCGK-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  乙酸钼(II)二聚体 、 1,5-bis(triisopropylsilyl)pentalene dipotassium salt 在 H₂O 作用下， 以 四氢呋喃 为溶剂， 以22%的产率得到[Mo2(η(5),η(5)-C8H4(1,4-Si(i)Pr3)2)]
  参考文献：
  名称：

  A Bimetallic Bis-pentalene Sandwich Complex:  Synthesis and Structure of Mo₂[C₈H₄(1,4-SiPrⁱ₃)₂]₂

  摘要：

  The reaction between K-2[C8H4(1,4-SiPr3i)(2)] and Mo-2(OAc)(4) yields Mo-2[C8H4(1,4-SiPr3i)(2)](2), the first example ofa bimetallic bis-pentalene sandwich complex to be structurally characterized by X-ray diffraction. Structural data show that the carbon frameworks of the two pentalene ligands are eclipsed and effectively planar with fold angles of ca. 2 degrees and 3 degrees while the SiPr3i groups are staggered the Mo-Mo distance is 2.340(1) Angstrom.

  DOI：

  10.1021/om980056q